Friday, October 25, 2019
Essay --
PET/ PETE:  Polyethylene Terephthalate  1.	Thermoplastic polymer in polyester family, with ââ¬Å"C10H8O4â⬠ as empirical formula for its monomer.  2.	It exists in two forms: fiber (synthetic) and resin.  3.	PET is converted into fiber form by permanent press fabric and bottles by blow molding.  4.	Recycling Code: #1  5.	PET is not biodegradable and its incineration produces harmful gases which have high potency to air pollution. Thatââ¬â¢s why recycling it for further use.    Properties [1]     Density	1.38 g/cc (20 ââÆ')  Young's Modulus	2800-3100 MPa  Tensile Strength	55-75 MPa  Elastic Limit	50-100%  Glass Transition Temperature	67-81	ââÆ'  Table 1: Properties of Poly-Ethylene Terephthalate.  6.	Strength and stiffness of PET exists because of the presence of large aromatic rings in the long chains which results in high resistant to deformation too [2].  7.	PET (waste) used as construction materials: Based on available research in the literature, waste PET (mainly bottles) is recycled in four major ways:  I.	Waste PET bottles depolymerized into unsaturated polyester resin to produce polymer mortar and polymer concrete [3].  Advantages:  â⬠¢	Higher compressive and flexural strength than normal Portland cement.  â⬠¢	Modified concrete achieves 80% of its ultimate strength within 1 day.  Disadvantages:  â⬠¢	Properties of modified cement sensitive to temperature.  â⬠¢	Cost for producing this modified concrete is high.    II.	PET Fiber to reinforce concrete [4].  Advantage:  â⬠¢	Enhances the ductility of quasi-brittle concrete.  â⬠¢	Reduce the cracking by plastic shrinkage.  Disadvantage:  â⬠¢	Water Repellent and low surface energy of plastic which result in weak mechanical bonding b/w fiber and concrete.  â⬠¢	Poor mechanical bond strength causes internal micro-cracks in the interfacial mechanical...              ...s Composites, 21(17): 1597ââ¬â1607, 2002.  16.	A. B. Inceoglu and U. Yilmazer. Synthesis and mechanical properties of unsaturated polyester based nanocomposites. Polym. Eng. Sci., 43(3): 661ââ¬â669, March 2003.  17.	M. S. Devi, V. Murugesan, K. Rengaraj, and P. Anand. Utilization of flyash as filler for unsaturated polyester resin. J. Appl. Polymer Sciences, 69(7): 1385ââ¬â1391, August 1998.  18.	A. B. Cherian and E. T. Thachil. Blends of unsaturated polyester resin with functional elastomers. J. Elastomer Plastics, 35(4):367ââ¬â380, October 2003.  19.	Y. Xu, M. L. Li, Y. Guo, and F. J. Lu. Structure and properties of modified unsaturated polyester resin by nano-TiO2. J. Mater. Sci. Technol., 19(6): 578ââ¬â580, November 2003.  20.	E. Kicko-Walczak. New ecological polyester resins with reduced flammability and smoke evolution capacity. J. Appl. Polym. Sci., 74(2):379ââ¬â382, October 1999.                            
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